Download PDF by Yoshio Waseda: Anomalous X-Ray Scattering for Materials Characterization

By Yoshio Waseda

ISBN-10: 3540434437

ISBN-13: 9783540434436

The evolution of our knowing of so much houses of latest sensible fabrics is said to our wisdom in their atomic-scale constitution. To extra this, numerous X-ray and neutron innovations are hired. The anomalous X-ray scattering (AXS) process, exploiting the so-called anomalous dispersion influence close to the absorption fringe of the constituent point, is among the strongest equipment for identifying the exact partial constitution capabilities of person pairs of elements or the environmental features round particular components in multicomponent platforms. AXS turns out to be useful for either crystalline and non-crystalline structures, for reviews of floor and bulk fabrics. This publication is the 1st in this new approach to structural characterization. It describes the fundamentals and alertness ideas, and likewise treats the specifics of program to liquid alloys, supercooled drinks, suggestions, steel glasses, oxide glasses, superconducting ionic glasses and so on.

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Extra resources for Anomalous X-Ray Scattering for Materials Characterization (Springer Tracts in Modern Physics)

Example text

Thus, the measurements of X-ray scattering intensity at an energy near the absorption edge of the constituent element gives an additional piece of information about the structure of the desired system. In order to facilitate the understanding of the anomalous dispersion effect for differentiating between two components, let us consider a sample containing Fe and Ni. Since the normal X-ray scattering factor is known to be proportional to the atomic number, the scattering ability may be approximated to be 26 for Fe and 28 for Ni.

Lamparter and S. Steeb: Z. , 37a, 1215 (1982) 33 16. T. Mizoguchi, T. Kudo, T. Irisawa, N. Watanabe, N. Niimura, M. Misawa and K. Suzuki: Proc. 3rd Int. Conf. on Rapidly Quenched Metals, Brighton (1978), The Metals Society (London), Cof. Proc. 198, (1978), pp. 384; J. Phys. Soc. , 45, 1773 (1978) 33 17. K. Yamada, Y. Endoh, Y. Ishikawa and N. Watanabe: J. Phys. Soc. , 48, 922 (1980) 33 18. E. A. M. North: Philos. , 14, 961 (1966) 33 19. J. J. J. Stewart: Philos. , 34, 721 (1976) 33 20. J. F. Phys.

6 shows a schematic for a spinel structure indicating two crystallographic non-equivalent cation sites. 10) x 2−x fZn + fFe . 0 correspond to the cation distribution of all zinc cations occupying the tetrahedral A-site and the octahedral B-site, respectively. When the intensities are measured at two energies, E1 and E2 , in the close vicinity of the absorption edge of a specific element such as Zn in the present case, the following simple but useful relation can readily be obtained: fB = 30 3. Nature of Anomalous X-ray Scattering Fig.

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Anomalous X-Ray Scattering for Materials Characterization (Springer Tracts in Modern Physics) by Yoshio Waseda


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